Active Carbon Absorption of Chemicals

Active Carbon Absorption of Chemicals

The Atmos 500 uses a three stage process to remove airborne contaminants. The first stage filters large particles, the second and activated carbon bed, the third is a HEPA filter (small particles).

Of the three the activated carbon stage is the most important for removing smells and potentially toxic out-gasses caused by the laser cutting process, and is most critical to the operation of the fabrication lab.

While most organic compounds will adsorb on activated carbon to some degree, the adsorption process is most effective on higher molecular weight and high boiling point compounds. Compounds having a molecular weight over 50 and a boiling point greater than 50 degrees centigrade are good candidates for adsorption 1)

These charts are adapted from More information about the Regeneration of Active Carbon - Lenntech

Chemicals with very high probability of being adsorbed by active carbon

<datatables>

2,4-DDeisopropyltatrazineLinuron
AlachlorDesethylatrazineMalathion
AldrinDemeton-OMCPA
AnthraceneDi-n-butylphthalateMecoprop
Atrazine1,2-DichlorobenzeneMetazachlor
Azinphos-ethyl1,3-Dichlorobenzene2-Methyl benzenamine
Bentazone1,4-DichlorobenzeneMethyl naphthalene
Biphenil2,4-Dichlorocresol2-Methylbutane
2,2-Bipyridine2,5-DichlorophenolMonuron
Bis(2-Ethylhexyl)Phthalate3,6-DichlorophenolNapthalene
Bromacil2,4-DichlorophenoxyNitrobenzene
BromodichloromethaneDieldrinm-Nitrophenol
p-BromophenolDiethylphthalateo-Nitrophenol
Butylbenzene2,4-Dinitrocresolp-Nitrophenol
Calcium Hypochloryte2,4-DinitrotolueneOzone
Carbofuran2,6-DinitrotolueneParathion
ChlorineDiuronPentachlorophenol
Chlorine dioxideEndosulfanPropazine
ChlorobenzeneEndrinSimazine
4-Chloro-2-nitrotolueneEthylbenzeneTerbutryn
2-ChlorophenolHezachlorobenzeneTetrachloroethylene
ChlorotolueneHezachlorobutadieneTriclopyr
ChryseneHexane1,3,5-Trimethylbenzene
m-CresolIsodrinm-Xylene
CyanazineIsooctaneo-Xylene
CyclohexaneIsoproturonp-Xylene
DDTLindane2,4-Xylenol

</datatables>

Chemicals with high probability of being adsorbed by active carbon

AnilineDibromo-3-chloropropane1-Pentanol
BenzeneDibromochloromethanePhenol
Benzyl alcohol1,1-DichloroethylenePhenylalanine
Benzoic acidcis-1,2- Dichloroethyleneo-Phthalic acid
Bis(2-chloroethyl) ethertrans-1,2- DichloroethyleneStyrene
Bromodichloromethane1,2-Dichloropropane1,1,2,2-Tetrachloroethane
BromoformEthyleneToluene
Carbon tetrachlorideHydroquinone1,1,1-Trichloroethane
1-ChloropropaneMethyl Isobutyl KetoneTrichloroethylene
Chlorotoluron4-MethylbenzenamineVinyl acetate

Chemicals with moderate probability of being adsorbed by active carbon

For these chemicals active carbon is only effective in certain cases.

Acetic acidDimethoateMethionine
AcrylamideEthyl acetateMethyl-tert-butyl ether
ChloroethaneEthyl etherMethyl ethyl ketone
ChloroformFreon 11Pyridine
1,1-DichloroethaneFreon 1131,1,2-Trichloroethane
1,2-DichloroethaneFreon 12Vinyl chloride
1,3-DichloropropeneGlyphosate
DikegulacImazypur

Chemicals for which adsorption with active carbon is unlikely to be effective

However it may be viable in certain cases such as for low flow or concentrations.

AcetoneMethylene chloride
Acetonitrile1-Propanol
AcrylonitrilePropionitrile
DimethylformaldehydePropylene
1,4-DioxaneTetrahydrofuran
Isopropyl alcoholUrea
Methyl chloride

Factors that influence the performance of active carbon in air

  • Type of compound to be removed: In general compounds with a high molecular weight, lower vapor pressure/higher boiling point and high refractive index are better adsorbed.
  • Concentration: The higher the concentration, the higher the carbon consumption.
  • Temperature: The lower the temperature, the better the adsorption capacity.
  • Pressure: The higher the pressure, the better the adsorption capacity.
  • Humidity: The lower the humidity, the better the adsorption capacity.

1) source: Wastewater Engineering; Metcalf & Eddy; third edition; 1991; page 317|



Read more: http://www.lenntech.com/library/adsorption/adsorption.htm#ixzz4880i9cJh

1)
www.carbtrol.com/voc.pdf|Shepard, 2001
facilities/fablab/equipment-cots/rayjet300/activated_carbon_absorption.txt · Last modified: 2018/07/23 14:27 by Michael Byrne
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